Okay just want to combine the two scripts. I have the list my all users email address script.
Get-Recipient | Select Name -ExpandProperty EmailAddresses | Select Name, SmtpAddress | Export-csv c:\AllStaffEmailAddress.csv
and the mailbox size script
Get-MailboxStatistics -Database "Mailbox Database XXXXXXXXXXXXX" | Select DisplayName, ItemCount, TotalItemSize | Sort-Object TotalItemSize -Descending | Export-CSV C:\MBSizes.csv